```{py:currentmodule} cantera ``` # Constant Pressure Reactor For this reactor model, the pressure is held constant and the energy equation is defined in terms of the total enthalpy. This model is implemented by the C++ class {ct}`ConstPressureReactor` and available in Python as the {py:class}`ConstPressureReactor` class. A constant pressure reactor is defined by the state variables: - $m$, the mass of the reactor's contents (in kg) - $H$, the total enthalpy of the reactor's contents (in J) - $Y_k$, the mass fractions for each species (dimensionless) Equations 1-3 below are the governing equations for a constant pressure reactor. ## Mass Conservation The total mass of the reactor's contents changes as a result of flow through the reactor's [inlets and outlets](sec-flow-device), and production of homogeneous phase species on [surfaces](sec-reactor-surface): $$ \frac{dm}{dt} = \sum_\t{in} \dot{m}_\t{in} - \sum_\t{out} \dot{m}_\t{out} + \dot{m}_\t{wall} $$ (constpressurereactor-mass) Where the subscripts *in* and *out* refer to the sum of the superscripted property over all inlets and outlets respectively. A dot above a variable signifies a time derivative. ## Species Equations The rate at which species $k$ is generated through homogeneous phase reactions is $V \dot{\omega}_k W_k$, and the total rate at which species $k$ is generated is: $$ \dot{m}_{k,\t{gen}} = V \dot{\omega}_k W_k + \dot{m}_{k,\t{wall}} $$ The rate of change in the mass of each species is: $$ \frac{d(mY_k)}{dt} = \sum_\t{in} \dot{m}_\t{in} Y_{k,\t{in}} - \sum_\t{out} \dot{m}_\t{out} Y_k + \dot{m}_{k,\t{gen}} $$ Expanding the derivative on the left hand side and substituting the equation for $dm/dt$, the equation for each homogeneous phase species is: $$ m \frac{dY_k}{dt} = \sum_\t{in} \dot{m}_\t{in} (Y_{k,\t{in}} - Y_k) + \dot{m}_{k,\t{gen}} - Y_k \dot{m}_\t{wall} $$ (constpressurereactor-species) ## Energy Equation Writing the first law for an open system gives: $$ \frac{dU}{dt} = - p \frac{dV}{dt} + \dot{Q} + \sum_\t{in} \dot{m}_\t{in} h_\t{in} - h \sum_\t{out} \dot{m}_\t{out} $$ where positive $\dot{Q}$ represents heat addition to the system and $h$ is the specific enthalpy of the reactor's contents. Differentiating the definition of the total enthalpy, $H = U + pV$, with respect to time gives: $$ \frac{dH}{dt} = \frac{dU}{dt} + p \frac{dV}{dt} + V \frac{dp}{dt} $$ Noting that $dp/dt = 0$ and substituting into the energy equation yields: $$ \frac{dH}{dt} = \dot{Q} + \sum_\t{in} \dot{m}_\t{in} h_\t{in} - h \sum_\t{out} \dot{m}_\t{out} $$ (constpressurereactor-energy)